Diastereoselective Pd-Catalyzed Anomeric C(sp<sup>3</sup>)–H Activation: Synthesis of α-(Hetero)aryl C-Glycosides
نویسندگان
چکیده
Anomeric C–H bond activation is an unsolved long-standing synthetic challenge. Herein, we report a diastereoselective Pd-catalyzed anomeric C(sp3)–H methodology that allows the synthesis of elusive C-(hetero)aryl glycosides with exclusive α-selectivity.
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2021
ISSN: ['2155-5435']
DOI: https://doi.org/10.1021/acscatal.0c05052